Propargyl p-toluenesulfonate
Propargyl p-toluenesulfonate is a functional initiator.
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Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to
24 months(2-8C).
Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.
Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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Macromolecular Chemistry and Physics, 2008, 209(18).
Clickable Poly(2-Oxazoline)s as Versatile Building Blocks.[Reference:
WebLink]
METHODS AND RESULTS:
Cationic ring-opening polymerization techniques are very sensitive to nucleophiles, which make it difficult to introduce different functional groups into these polymers. Clickable poly(2-oxazoline)s were synthesized and functionalization was performed by the copper(I)-catalyzed 1,3-dipolar cycloaddition between alkynes and azides. Therefore, an alkyne function is introduced into the polymer backbone by utilizing alkyne toluene-4-sulfonates as an initiator. The polymerization kinetics were investigated for four different 2-substituted-2-oxazolines and well-defined acetylene-functionalized poly(2-ethyl-2-oxazoline)s with different lengths were synthesized having 100% functionality.
CONCLUSIONS:
One of these polymers was used to demonstrate its applicability in the azide-alkyne click reaction by reaction with different azide compounds.
