(-)-Isodocarpin
Reference standards.
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Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to
24 months(2-8C).
Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.
Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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Related and Featured Products
Angewandte Chemie International Edition.
Divergent Total Syntheses of Enmein-Type Natural Products:(-)-Enmein, (-)-Isodocarpin and (-)-Sculponin R.[Reference:
WebLink]
METHODS AND RESULTS:
Divergent total syntheses of enmein-type natural products, (–)-enmein, (-)-Isodocarpin and (–)-sculponin R,
have been achieved in a concise fashion.
CONCLUSIONS:
Key features of the strategy include (a) an efficient early-stage cage
formation to control succeeding diastereoselectivity, (b) an one-pot acylation/akylation/lactonization to
construct the C-ring and C8 quarternary center, (c) a reductive alkenylation approach to construct enmain D/E
rings and (d) a flexible route to allow divergent syntheses of three natural products.
