Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to
24 months(2-8C).
Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.
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The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
Bulletin of the Chemical Society of Japan, 1990, 63(9):2540-2548.
Syntheses and Reactions of Conjugated Dienic Thioketones.[Reference:
WebLink]
METHODS AND RESULTS:
5,6-Dihydro-2-phenyl-3-thiobenzoyl-2H-naphtho[1,2-b]thiin (8a) and the related dienic thioketones were synthesized in 3 steps starting from 2-(phenylthio)methylenetetralin-1-thione with chalcone, 4′-chrolochalcone, 4'-Methoxychalcone, 2-cinnamoylthiophen, 2-cinnamoylfuran, 1-phenyl-2-buten-1-one, and acrylophenone respetively. Similarly, 3-thiobenzoyl-2,6-diphenyl-2H-thiin (8i) was synthesized from 1-phenyl-3-phenylthio-2-propene-1-thione. All of these dienic thioketones were found to exist in stable monomeric form. The conjugated dienic thioketone (8a) reacted as α,β-unsaturated thioketone with 2-norbornene, 2,5-norbornadiene, diethyl azodicarboxylate, diphenyl fumarate, N-phenyl- and N-(p-tolyl)maleimides, 2-chloroacrylonitrile, methyl methacrylate, acrylonitrile, and styrene to give the corresponding [4+2]cycloadducts. The thioketone (8i) also reacted with 2-norbornene to give the corresponding cycloadduct.
CONCLUSIONS:
The reaction provides a useful method for the syntheses of various sulfur-containing heterocycles.
