Benzamide

Benzamide
Product Name Benzamide
CAS No.: 55-21-0
Catalog No.: CFN98925
Molecular Formula: C7H7NO
Molecular Weight: 121.1 g/mol
Purity: >=98%
Type of Compound: Alkaloids
Physical Desc.: Powder
Source: The herbs of Berberis pruinosa
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Price:
Reference standards.
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Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C).

Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.

Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com

The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
  • J. of The Korean Society of Food Culture2017, 144-149
  • Planta Med.2023, a-2192-2281.
  • Sci Rep. 2017, 12953(7)
  • Mol Cells.2015, 38(9):765-72
  • Front Pharmacol.2018, 9:756
  • Eur J Neurosci.2021, 53(11):3548-3560.
  • JMSACL2023, 09.002
  • Int J Mol Sci.2021, 22(8):4211.
  • Sains Malaysiana2024, 53(2):397-408.
  • Agronomy2023, 13(6), 1435.
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    METHODS AND RESULTS:
    Density functional theory has been applied to gain insight into the Cp*Rh(OAc)2-catalyzed C-H activation and intermolecular annulation of Benzamide derivatives with allenes. The study shows that the reactions proceed in three steps: (1) C-H activation induced by Rh catalyst reacting with Benzamide derivatives, (2) carborhodation of allene, and (3) regeneration of Rh catalyst. The results indicate that the N-H deprotonation makes the following C-H activation much easier. The regio- and stereoselectivities of 1a (N-pivaloyloxy Benzamide)/2a (cyclohexylallene) and 1b (N-pivaloyloxy-4-methyl-Benzamide)/2b (1,1-dimethyl allene) depend on the allene carborhodation step. The steric hindrance effect is the dominant factor. We also discuss the reaction mechanism of 1c (N-methoxy Benzamide)/2a.
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