Acetylcytisine
N-Acetylcytidine is the Anti-Herbal Chemical Defense Compound in Genista.
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Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to
24 months(2-8C).
Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.
Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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J Chem Ecol . 1993 Mar;19(3):441-448.
Quinolizidine alkaloids inGenista acanthoclada and its holoparasite,Cuscuta palaestina[Pubmed:
24248948]
About 20 quinolizidine alkaloids were identified inGenista acanthoclada by capillary GLC and GLC-MS, such as sparteine, 11,12-dehy-drosparteine, retamine,N-methylcytisine, cytisine, 17-oxosparteine, lupanine,α-isolupanine, 5,6-dehydrolupanine, 10-oxosparteine,N-carbomethoxycytisine, 17-oxoretamine,N-formylcytisine,N-Acetylcytisine, and anagyrine. Its phloem-feeding holoparasiteCuscuta palaestina contained alkaloids too, such as sparteine, 11,12-dehydrosparteine, retamine,N-methylcytisine, cytisine, 17-oxosparteine, lupanine,N-carbomethoxycytisine, and anagyrine. Whereas sparteine, retamine, 17-oxosparteine, and cytisine are the main alkaloids ofG. acanthoclada, lupanine, cytisine,N-methylcytisine, and anagyrine are abundant and enriched inC. palaestina. Since these alkaloids figure as antiherbivoral chemical defense compounds inGenista, it is assumed that the parasite can exploit the acquired allelochemicals for its own protection.
Rapid Commun Mass Spectrom . 2007;21(8):1409-1413.
Electron ionization mass spectral study of selected N-amide and N-alkyl derivatives of cytisine[Pubmed:
17370243]
(-)-Cytisine and its derivatives are promising alkaloids in the development of new drugs for the treatment of disorders of the central nervous system (CNS). Electron ionization (EI) mass spectral fragmentations of cytisine (1), N-methylcytisine (2), N-ethylcytisine (3), N-Acetylcytisine (4), N-propionylcytisine (5) and N-benzoylcytisine (6) have been investigated. Detailed fragmentation pathways have been identified for all significant ions, including a few characteristic fragment ions. The principal fragmentation routes of compounds 1-6 have been determined on the basis of EI low-resolution, high-resolution and B2/E linked scans as well as linked scans at constant B/E.
