Bicyclo[5.3.0]decapentaene
Reference standards.
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Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to
24 months(2-8C).
Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.
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The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2001, 17(0z1):P.128-108,39.
Novel Chiral Auxiliaries of BIAZOLs.[Reference:
WebLink]
Asymmetric catalysis is one of the most challenging and formidable endeavor in organic synthesis. The development of chiral auxiliaries is a key in the asymmetric catalysis.
METHODS AND RESULTS:
Azulenoids, a parent structure of
Bicyclo[5.3.0]decapentaene with 10 πelectrons, are useful as dye materials, medical treatment of inflammation and hypertension, and the development of liquid crystals. In continuing to investigate synthetic application of azulenoids, we have studied to develop novel chiral auxiliaries of BIAZOLs.
CONCLUSIONS:
The BIAZOLs were synthesized from dicyclopentadiene and characterized using spectroscopies.