Apigenin 6-C-alpha-L-arabinopyranosyl-8-C-beta-D-xylopyranoside

Chinese Journal of Experimental Traditional Medical Formulae, 2013, 19(21):77-81.

Chemical Constituents of Viola yedoensis and Their Antioxidant Activity.[Reference: WebLink]

To investigate the chemical constituents of Viola yedoensis and their antioxidant activity.
METHODS AND RESULTS:
A systematic isolation was performed by various column chromatography with the n-butanol fraction of the ethanolic extract of the herb. Eleven compounds were isolated and identified as kaempferol-3-O-β-D-sophorosyl-7-O-α-L-rhamnopyrano-side(1),kaempferol-3,7-di-O-α-L-rhamnopyranoside(2),apigenin-6,8-di-C-β-D-glucopyranoside(3),adenosine(4),esculetin(5),Apigenin 6-C-alpha-L-arabinopyranosyl-8-C-beta-D-xylopyranoside(6),apigenin-6-C-β-D-glucopyranosyl-8-C-α-L-arabinopyranoside(7),apigenin-6-C-β-D-glucopyranosyl-8-C-β-D-xylopyranoside(8),apigenin-6,8-di-C-α-L-arabinopyranoside(9),apigenin-6-C-β-D-glucopyranosyl-8-C-β-L-arabinopyranoside(10) and kaempferol-3-O-β-D-glucopyranosyl-7-O-α-L-rhamnopyranoside(11),respectively. All compounds were evaluated for antioxidant capacity against DPPH radicals,and compounds 1-5 and 11 showed antioxidant activities.
CONCLUSIONS:
Compound 2 was reported from Viola yedoensis for the first time,and compounds 1 and 8 were the first time to be isolated from the genus Viola.

Chem Pharm Bull (Tokyo). 2003 Oct;51(10):1204-7.

Flavone C-glycosides from Viola yedoensis MAKINO.[Pubmed: 14519932]

METHODS AND RESULTS:
A new flavone C-glycoside, apigenin 6-C-alpha-L-arabinopyranosyl-8-C-beta-L-arabinopyranoside, has been isolated from Viola yedoensis together with the known compounds, apigenin 6,8-di-C-alpha-L-arabinopyranoside, apigenin 6-C-alpha-L-arabinopyranosyl-8-C-beta-D-glucopyranoside (isoschaftoside), apigenin 6-C-beta-D-glucopyranosyl-8-C-alpha-L-arabinopyranoside (schaftoside), apigenin 6-C-beta-D-glucopyranosyl-8-C-beta-L-arabinopyranoside (neoschaftoside), apigenin 6,8-di-C-beta-D-glucopyranoside (vicenin-2), Apigenin 6-C-alpha-L-arabinopyranosyl-8-C-beta-D-xylopyranoside, apigenin 6-C-beta-D-xylopyranosyl-8-C-alpha-L-arabinopyranoside, luteolin 6-C-beta-D-glucopyranoside (isoorientin) and luteolin 6-C-alpha-L-arabinopyranosyl-8-C-beta-D-glucopyranoside (isocarlinoside).
CONCLUSIONS:
The structures were determined by spectroscopic methods and new or revised (1)H- and (13)C-NMR spectral assignments are proposed for some compounds.