Acerogenin G
Acerogenin G is a natural product from Acer nikoense.
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Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to
24 months(2-8C).
Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.
Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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Tetrahedron, 2013, 69(13):2807-2815.
Total synthesis of acerogenins E, G and K, and centrolobol.[Reference:
WebLink]
METHODS AND RESULTS:
The first total synthesis of the diarylheptanoid acerogenins E and K, isolated from Acer nikoense MAXIM., is described. Formation of the 13-membered m,m-cyclophane skeleton was successfully achieved on the basis of a domino process involving a Miyaura arylborylation–intramolecular Suzuki reaction. The cyclization precursor was prepared via a Wittig reaction and Claisen–Schmidt condensation, which proceeded in moderate yields.
CONCLUSIONS:
The total synthesis of Acerogenin G and centrolobol was also achieved from a common synthetic intermediate.
